KINETIC STUDIES OF THE ADSORPTION OF HEAVY METAL(CHROMIUM) FROM INDUSTRIAL WASTE WATER USING PALM KERNEL SHELLS


KINETIC STUDIES OF THE ADSORPTION OF HEAVY METAL(CHROMIUM) FROM INDUSTRIAL WASTEWATER USING PALM KERNEL SHELLS 

ABSTRACT

Palm kernel shells are readily available agricultural waste products that have been used as low-cost potential adsorbent to remove chromium from effluent water. The production of activated carbon from palm kernel shells using KOH as activating agent was studied. Batch adsorption studies were carried out as a function of parameters such as carbon dosage, pH and contact time. Chromium removal was found to be pH dependent with the optimum pH for chromium removal being 6.5. Equilibrium time was attained at 200 min. Maximum adsorption was attained at an adsorbent loading of 5g. The Lagergrenpseudo first-order and the Ho pseudo second-order models were used to study adsorption kinetics. Pseudo first order kinetics was found to be better fit for adsorption chromium(III) ions with good correlation factor of 0.965. These results reveal that activated carbon made from palm kernel shells possesses good properties required for adsorption of heavy metal ions from aqueous solution.

TABLE OF CONTENTS

DECLARATION i

CERTIFICATION i

DEDICATION ii

ACKNOWLEDGEMENT iii

ABSTRACT iv

LIST OF FIGURES viii

LIST OF TABLES ix

CHAPTER ONE 1

INTRODUCTION 1

1.1 Background of study 1

1.2 Statement of the problem 2

1.3 Aim and objectives 2

1.3.1 Aim 2

1.3.2 Objectives 2

1.4 Significance of work 3

1.5 Scope of work 3

CHAPTER TWO 4

LITERATURE REVIEW 4

2.1 Introduction 4

2.2 Adsorption 4

2.2.1 Definition of adsorption 4

2.2.2 Adsorption processes 4

2.2.3 Types of adsorption 5

2.2.4 Comparison of physical and chemical adsorption process 5

2.2.5 Applications of adsorption 6

2.3 Activation 8

2.3.1 Physical activation 8

2.3.2 Chemical activation 8

2.4 Activated carbon 9

2.4.1 Definition of activated carbon 9

2.4.2 Classification of activated carbon 9

2.4.3 Activated carbon production 10

2.4.4 The mechanism of adsorption 11

2.5 Characteristics of palm kernel shell 12

2.6 Adsorption kinetics 12

2.6.1 Kinetic models 13

2.6.2 Isotherm model 14

2.7 Industrial wastewater 16

2.7.1 Effects of industrial pollutants on life 16

2.7.2 Chromium 17

2.8 Review of past work done on adsorption of heavy metals wastewater 18

CHAPTER THREE 21

MATERIALS AND METHOD 21

3.1 Raw material 21

3.2 Equipment and reagents 21

3.2.1 Equipment 21

3.2.2 Reagents 22

3.3 Activating agent 22

3.3.1 Potassium hydroxide solution preparation 22

3.4 Preparation of activated carbon 23

3.4.1 Washing 23

3.4.2 Size reduction 23

3.4.3 Dehydration 23

3.4.4 Carbonization 23

3.4.5 Chemical activation 23

3.4.6 Washing and drying 24

3.5 Potassium dichromate solution preparation 24

3.6 Characterisation of activated carbon 25

3.6.1 Determination of pH 25

3.6.2 Determination of ash content 25

3.6.3 Determination of moisture content 25

3.6.4 Determination of bulk density 26

3.7 Experimental method 26

3.7.1 Effect of adsorbent dosage 27

3.7.2 Effect of pH 27

3.7.3 Effect of contact time 27

3.8    Adsorption kinetics 28

CHAPTER FOUR 29

RESULTS AND DISCUSSION 29

4.1 Activated carbon preparation results 29

4.2 Characterization of the activated carbon 29

4.2.1 pH 29

4.2.2 Bulk density 30

4.2.3 Moisture content 30

4.2.4 Ash content 30

4.3 Results of adsorption process 31

4.3.1 Effect of absorbent dosage 32

4.3.2 Effect of pH 33

4.3.3 Effect of contact time 34

4.4 Chromium ion adsorption analysis 35

4.5 Kinetic studies 36

4.5.1 Lagergren pseudo first-order equation 36

4.5.2 Ho Pseudo second-order equation 38

CHAPTER FIVE 41

CONCLUSION AND RECOMMENDATION 41

5.1 Conclusion 41

5.2 Recommendation 41

REFERENCES 42

APPENDIX 45

1 Activated carbon yield 45

2 Activated carbon characterization 45

3 Adsorption of activated carbon 46

4 Effect of contact time 49

5 Lagregren pseudo first-order calculations 52

6 Ho pseudo second-order calculations 54

CHAPTER ONE

INTRODUCTION

1.1 Background of study

Activated carbon is a carbonaceous and crystalline material with a high surface area that makes it appropriate for adsorbing chemical substances that contaminate water or air, depending on its structure. Activated carbon is a microcrystalline, non-graphite form of carbon with porous structure that has been processed to develop its internal porosity, and characterized by large specific surface area of 500-2500m2/g. It is a versatile adsorbent with wide range of uses and applications. The most commonly known use of activated carbon is the purification of water sources. Activated carbon filter is one of several systems used to purify water drawn from wells and springs for home use. It is most effective in the removal of organic substances from water. Its porosity multiplies the surface available to adsorb toxins or react with chemicals (Musal, 2011).

Several agricultural wastes products have been found useful in activated carbon production, like palm kernel shell, coconut shell, rise husk, groundnut husk, cassava peel, maize cob, banana pith, medicagosativa (Alfalfa), sphagnum moss peat, sunflower stalks and others (Nwankwo et al., 2014). Activated carbon can be produced in abundance from oil palm endocarp (or oil palm kernel shell) which is an abundant agricultural solid waste from palm-oil processing mills in many tropical countries such as Nigeria, Malaysia, and Thailand (Silgado et al., 2014).

 The use of palm shell as an adsorbent is beneficial because ordinarily, palm shells are considered as waste in many parts of Nigeria, so utilizing them to produce activated carbon is an effective waste management practice. This recycle plan is better than dumping them to pollute the environment or cause environmental or disposal problems. Another reason why producing activated carbon from agricultural waste is beneficial is because it is very economical especially in a country like Nigeria. So there is no need to worry about purchasing expensive equipment and chemicals to remove chemical waste.

Being a good adsorbent of chemical compounds from industrial waste effluent, activated carbon produced from agricultural products can be used to remove heavy metals from industrial waste water. Different physical and chemical processes are available for removal of heavy metals fromwastewater, such as co-precipitation, coagulation, evaporation recovery process, electrolyticrecovery, electro-chemical precipitation, ultra-filtration, ion exchange, reverse osmosis and biological techniques. A major drawback with precipitation is sludge formation. Ion exchange is a better alternative technique for such purpose, but it is not economically appealing because of high operational cost. The use of activated carbon for the removal of toxic metal ion pollutants and numerous other organic materials from both gases and aqueous solutions is of considerable importance. Activated carbon has proven to be an efficient and cost effective adsorbent (Musah, 2011).

On the other hand, the kinetics of the adsorption process will enable one to determine the rate as well as the mechanism of adsorption processes (Okafor et al., 2015).

1.2 Statement of the problem

The release of heavy metals into the environment through industrial effluent is a major concern worldwide and removal of such pollutants has been of great concern during the last decades. Heavy metals can pose health hazards to man and aquatic lives. Wastewater commonly contains Chromium, lead, Copper and Nickel ions. These heavy metals are not biodegradable and their presence in stream, lakes leads to bioaccumulations in living organisms, causing health problems in animals, plants and human beings. Therefore, it is of prime importance to remove heavy metals from wastewater that is to be discharged to water bodies.

1.3 Aim and objectives

1.3.1 Aim

To study the kinetics of the adsorption of heavy metal from industrial waste water using palm kernel shells.

1.3.2 Objectives

1. To prepare a low-cost adsorbent from palm kernel shells.

2. To activate the adsorbent prepared from palm kernel shells.

3. To study the kinetics of the adsorption process.

4. To determine the efficiency of palm kernel shells as an environmentally friendly adsorbent.

5. To characterize activated carbon made from palm kernel shells.

1.4 Significance of work

With rapid increase in industrial activities, pollution due to the presence of heavy metals in water and wastewaters has been a major cause of concern for environmental engineers. Several episodes of heavy metal contamination in aquatic environment have increased the awareness about heavy metal toxicity. Among these, Minamata tragedy due to mercury poisoning and “Itai-Itai” disease in Japan due to cadmium toxicity are well known. More recently cases of lead poisoning were reported in Zamfara State, Nigeria; which led to the death of several people and animals as a result of lead contamination of water bodies (streams and rivers) and the environment. The presence of heavy metals in the environment is thus of major concern because of their extreme toxicity and tendency for bioaccumulation in the food chain even in relatively low concentration (Adie et al., 2012). So it has become necessary to develop low-cost adsorbent for the removal of heavy metals from industrial effluent. This research work gives the step by step procedure on developing a low-cost adsorbent from palm kernel shells.

1.5 Scope of work

Although there are several agricultural products (e.g. coconut shell, maize cob, rise husk) used in producing activated carbon, this work only focuses on the use of activated palm kernel shell as heavy metal adsorbent. Heavy metals in industrial wastewater are numerous (e.g. lead ions, cadmium ions, etc.) but this study will only investigate the kinetics of the removal of chromium ion from industrial effluent using palm kernel shells.

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KINETIC STUDIES OF THE ADSORPTION OF HEAVY METAL(CHROMIUM) FROM INDUSTRIAL WASTE WATER USING PALM KERNEL SHELLS



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